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PMMH’s weekly seminar is held every Friday at 11 am (map)
Stéphane Perrard
Etienne Reyssat
Virgile Thiévenaz
PMMH
BARRE CASSAN
BAT A 1ER ETAGE CASE 18
7 QUAI SAINT BERNARD
75005 PARIS
France
Tel : (33) 1 40 79 45 22
Séminaire PMMH - Chinar Rana (ULB, Bruxelles)
Effects of adsorption and viscous fingering instability on the dispersion and the form of the peaks in liquid chromatography
Liquid chromatography is a flow based separation method where, a given fluid (called eluent) displaces a miscible sample consisting of a solvent in which a mixture of solutes (also named analytes) is dissolved. The analytes are separated during the displacement because of the selective adsorption on the porous matrix and/or selective transport properties. The fluid flow in a porous medium and the adsorption of the solutes play an important role in these separation techniques. The solutes are retained on the stationary phase of the column following linear or non-linear adsorption isotherm. In addition to this, when the viscosity of the sample injected in a liquid chromatographic column is different from that of the carrier liquid, a hydrodynamic instability called viscous fingering occurs at that sample/carrier interface where the more viscous fluid is displaced by the less viscous one. These two phenomena sometimes result in significant peak broadening and distortion of the shape. We undertook a numerical study of these phenomena in analytical and preparative liquid chromatography. Depending on the parameters involved, the evolution of the distribution of the analyte along the column is observed to show different features for instance : bimodality (two peaks), shock layer, and rarefaction.
Figure : (left) Linear adsorption with solvent strength effect showing bimodal and distorted peaks. (right) Non-linear adsorption of Langmuir type showing rarefaction and shock layer formation.
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Seminars (4)
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Séminaire PMMH - Francesca Borghi Università degli Studi di Milano
Vendredi 20 juin de 11h00 à 12h00 - Salle réunion PMMH 1
REPROGRAMMABLE HARDWARE FOR DATA PROCESSING AT THE EDGE : A NEW COMPUTING PARADIGM BASED ON NEUROMORPHIC SYSTEMS
The brain's ability to perform efficient and fault-tolerant data processing is strongly related with its peculiar interconnected adaptive architecture, based on redundant neural circuits interacting at different scales. By emulating the brain's processing and learning mechanisms, computing technologies strive to (…) -
Séminaire PMMH - Francesca Borghi Università degli Studi di Milano
Vendredi 20 juin de 11h00 à 12h00 - Salle réunion PMMH 1
REPROGRAMMABLE HARDWARE FOR DATA PROCESSING AT THE EDGE : A NEW COMPUTING PARADIGM BASED ON NEUROMORPHIC SYSTEMS
The brain's ability to perform efficient and fault-tolerant data processing is strongly related with its peculiar interconnected adaptive architecture, based on redundant neural circuits interacting at different scales. By emulating the brain's processing and learning mechanisms, computing technologies strive to (…) -
Séminaire PMMH - Salvatore Federico (University of Calgary, Canada)
Vendredi 4 juillet de 11h00 à 12h00 - Salle réunion PMMH 1
Continuum Mechanics of Hydrated Fibre-Reinforced Soft Tissues
Biological tissues can be represented as bi-phasic continua, with a porous solid phase saturated by an interstitial fluid and reinforced by collagen fibers. This lecture will give an overview of the modelling techniques for fibre-reinforced porous composite materials with statistical orientation of the fibers. Both (…) -
Séminaire PMMH - Salvatore Federico (University of Calgary, Canada)
Vendredi 4 juillet de 11h00 à 12h00 - Salle réunion PMMH 1
Continuum Mechanics of Hydrated Fibre-Reinforced Soft Tissues
Biological tissues can be represented as bi-phasic continua, with a porous solid phase saturated by an interstitial fluid and reinforced by collagen fibers. This lecture will give an overview of the modelling techniques for fibre-reinforced porous composite materials with statistical orientation of the fibers. Both (…)
The audience is composed of people with rather heterogeneous backgrounds including specialists in solids, fluids, granular flows, statistical physics... so the idea is to keep your talk understandable by people not necessarily working in your field... The seminar time slot runs from 11am to noon so the best is to make the talk last around 45 minutes to leave some time for discussion.
- Séminaires ESPCI-ENS de biophysique
- Séminaires du Département de Physique de l’ENS
- Séminaires du Laboratoire d’Hydrodynamique de l’X
- Séminaire de Mécanique d’Orsay (page web FAST)
- Séminaire de Mécanique d’Orsay (page web LIMSI)
- Séminaire de Mécanique des Fluides de l’Institut Jean le Rond d’Alembert
- Séminaires du laboratoire MSC, Paris VII
- Séminaires Gulliver
Link to cofee seminar (internal, every Thursday)
